The Ballon d'Or winner won a record 126th cap in the Nations League fixture on Thursday evening after being named in the starting line-up.
Kane's latest cap took him past former England goalkeeper Peter Shilton's long-standing record of 125 caps.
Shilton - who had held the record since 1989 - and Prince William made a presentation to Kane on the pitch before the game. Kane was handed a commemorative shirt with 126 on the back along with a plaque to mark the occasion.
The Bayern Munich striker marked the historic occasion with a goal, scoring a second-half penalty after Jarell Quansah was fouled in the box to take his tally for his country to 92.
Speaking to ITV, Kane said: "An incredible gesture at the start of the game, but it was all about getting the win.
"They are a tough team who wanted to prove something. For large spells we did well, but got a little tired. It sets up a great game [against Spain] on Sunday."
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England head coach Thomas Tuchel wrote in his programme notes: "It's the perfect place to celebrate Harry Kane and his recent achievements.
"There's something quite poetic about the fact that almost a week or so after he was named England's first Ballon d'Or winner for over 25 years, he's now on the cusp of becoming the country's all-time record caps holder.
"It's so special, not just for Harry, but for all of us."
Building manager James Stuart, 46, from northwest Washington DC, was killed just before 8am on Thursday, Metropolitan Police Department interim Chief Jeffery Carroll told reporters.
The gunman - identified as Matt Lambert, a doctor - wounded four others at the VIDA Fitness gym before barricading himself in his apartment and turning the gun on himself, law enforcement officials have said.
Chief Carroll said: "We do know that there has been an ongoing dispute between the suspect in this case and the homeowners association management regarding maintenance issues, mould and the like.
"There was a civil case that he filed against them. So we believe that it's related to that."
One of the wounded is in a critical condition, Chief Carroll added. The three others have non-life-threatening injuries.
Sky has learnt that Lambert had owned and lived in the apartment, which has an estimated value of more than $1m (£755,000), since 2016.
An account on X, believed to be Lambert's, posted 200 times about issues with his apartment building over a 13-month period. A "manifesto" was posted by the account shortly after the shooting.
James Spellman, who was at the gym, said there were about 50 people inside when the shooting began.
"Within seconds there was a man who fell to the ground, and a pool of blood came out," he said. "One gym member rushed to help him. He was instantly dead. He had been shot in the neck."
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Officers had arrived on the scene within seconds of the initial call, Chief Carroll said.
While clearing a nearby residential building, police heard gunfire coming from the seventh floor, where the suspect had holed himself up in his own apartment.
Negotiators heard a gunshot while talking to him on the phone during a standoff.
"He did fire through the door at officers, at least on two occasions, while he was barricaded inside," Chief Carroll told a news conference.
When officers forced their way into the flat, the suspect was found dead from a self-inflicted gunshot wound.
Washington Mayor Muriel Bowser praised the swift law enforcement response to what she described as a "senseless act of gun violence", adding that the White House had been briefed.
Daniel Rayner, 42, of Whitstable, Kent, is one of nine men on trial who face various allegations in relation to sexual offending against the woman.
The woman's husband, who's in his 60s and cannot be identified to protect his wife's anonymity, has pleaded guilty to dozens of offences dating back to 2004, including rape and administering a substance with intent to commit a sexual offence.
At the couple's home in Stockport, Greater Manchester, the husband took images and videos of the abuse while she was "out of it" on their bed and shared them online, the jury heard.
Prosecutors read out an exchange between the husband and Rayner, which they said took place on the Telegram app in 2024.
Rayner is said to have messaged: "Hi mate. How's it going? I've just got back on here. Hope you still having fun with your sexy wife?"
The husband replied: "When I get the chance."
Rayner came back with: "I'd love to give you some of my special serum to see her totally out of it for a while.
"Have you taken any pics or vids recently mate? I've lost all the groups you posted her in.
"I can't seem to find any of the sleep groups any more. Do they still exist or have they changed names or gone private?"
Manchester Minshull Street Crown Court heard that Rayner, a few months later, told the husband he could get GHB, often referred to as a "date-rape drug".
The husband wrote: "It's a shame you're so far away" - to which Rayner allegedly replied: "Always willing to drive for some fun."
The court heard that in 2022 Rayner had bought a "sleeping liquid" labelled as "hair serum" from a website selling sexual wellness products and sleep aids.
Items available - listed in English and Chinese - were said to include "amnesiac properties so no memory during sleeping process and no side effects".
Rayner allegedly bought more bottles of the substance the following year.
The 42-year-old denies rape, conspiracy to assault by penetration, and conspiracy to administer a substance with intent.
The husband was arrested in October 2025 after German journalists infiltrated a Telegram group for people interested in sex with someone asleep or unconscious.
A phone seized from his address is said to have contained one million photographs and videos of the abuse by him and other men.
His internet browsing history between 2014 and 2025 also revealed many searches for medication and drugs, the jury heard.
He will give evidence against the defendants later this month in court.
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Alleged contact offenders, said to have visited his home to commit sexual offences including rape, are:
Philip Wild, 59, of Stockport; Mohammed Sabir, 28, of Stockport; Jordan Wallace, 31, of Wythenshawe; Alan Keelan, 42, from Wythenshawe; Robert Stewart, 70, of Stockport; Richard Townsend, 38, of Heywood, Greater Manchester; and Jonathan Kirk, 43, of Stockport.
Non-contact offenders, who allegedly "hid behind a screen", are Rayner and kitchen firm sales rep David Graves, 60, from Ilkeston, Derbyshire.
All nine deny the allegations.
Four other men have admitted offences. They are: Graham Brougham, 74, from Northwich, Cheshire; Sean Peers, 38, from Stockport; Keith Fotheringham, 59, from Dundee, and Karl Lindsay, 56, from Taunton, Somerset.
The National Crime Agency (NCA) said Mudasar Hussain and Kamir Ifzal Khan, both 37, absconded ahead of their trial and at least one has fled abroad.
The pair were found guilty along with Mudasar's brother, Ghazanfar Hussain, 42, at Sheffield Crown Court on Thursday.
Mudasar Hussain had been on conditional bail ahead of his trial and had been forced to give up his passport.
The NCA said he could still be in the UK, but he may have left the country illegally.
Khan, who had also been on conditional bail, flew to Qatar on 22 September and is believed to have gone on to Pakistan.
Mudasar Hussain was convicted of 12 counts of rape; Khan of two counts of rape and one count of sexual exploitation; and Ghazanfar Hussain of one count of rape.
The victim was 13 and 14 when she was groomed and sexually abused - first by Mudasar Hussain, then separately by Ghazanfar Hussain and Khan between 2008 and 2010.
Mudasar Hussain, about 20 at the time, plied her with alcohol and drugs and after a few months took her to a house in Rotherham where he raped her.
He abused her "countless times over the course of around 18 months, at the house, in local public spaces and in his car," said the NCA.
She told police he violently coerced her, including threatening her with a baseball bat.
His brother Ghazanfar Hussain - nicknamed Gucci and around 24 at the time - raped her on one occasion when his brother left the country for a period.
The victim didn't know at the time they were related.
Khan began abusing the girl when she started going to a takeaway he worked at, according to the NCA. He gave her food, money and cigarettes and took her out on deliveries.
She thought they were in a relationship, but he raped her during a period of abuse lasting around seven months.
The NCA said he also took her to a house on a number of occasions and asked her to have sex with other men who were there.
She always refused, but one day he took her to another address and left her alone with another man, who raped her.
Khan later told the girl he owed the man a favour.
The three men were arrested as part of Operation Stovewood, established in 2014 in the wake of the Rotherham exploitation scandal.
The NCA said the probe had identified and supported around 1,150 potential victims and secured 60 convictions against 55 people.
Khan and the Hussain brothers will be sentenced at Sheffield Crown Court on Friday.
Officers are appealing for the public's help to find the two who are on the run.
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Head of Operation Stovewood Philip Marshall said: "The victim has shown tremendous courage in reporting the predatory grooming, exploitation and sustained sexual abuse these men subjected her to as a child."
Anyone with information on is urged to report it anonymously to Crimestoppers by calling 0800 555 111 or via its website.
A civil court ruled in 2017 that the former footballer and former teammate David Robertson raped Denise Clair at a property in West Lothian following a night out in 2011, but no criminal charges were filed against the pair.
Goodwillie has insisted he is innocent and has previously told a podcast he wanted to move on with his life.
Robertson denied any wrongdoing during the civil suit.
Ms Clair, who has waived her right to anonymity, is seeking a private prosecution against Mr Goodwillie - a rare process in the Scottish legal system.
Known formally as a Bill for Criminal Letters, it involves an individual or organisation seeking to prosecute the accused, rather than the Crown Office taking action.
The Lord Justice General Lord Pentland is chairing a panel of three judges who are considering the bill.
After hearing legal arguments in favour and against the proceedings at the Criminal Appeal Court in Edinburgh on Thursday, he said they "will take some time to consider submissions" and will "issue a judgment as soon as practicable".
Advocate Depute Alan Cameron earlier said the Crown could not agree to the bill.
He stated: "In relation to the test set down by this court, the Lord Advocate submits that there are no exceptional circumstances which would permit the issuing of a Bill of Criminal Letters."
Mr Cameron said it is "fundamentally different" from a court deciding whether to grant a judicial review because of the requirement for "exceptionality" when deciding whether to allow a Bill of Letters.
Lord Pentland said: "The fundamental reason why the bar has to be set at such a high standard is a reflection of the different constitutional responsibilities of the Lord Advocate and the court."
The court also heard that Goodwillie (the respondent) gave evidence during the civil case and this could in theory be used at any potential private prosecution.
Mr Cameron said: "The respondent gave detailed evidence under oath at the civil proof.
"The evidence is in theory admissible but whether it would in fact be admitted would be a matter for the trial judge."
In written submissions to the court, Ms Clair's lawyer Thomas Ross KC argued that the decisions taken by a previous Lord Advocate that there was "insufficient evidence to prove lack of consent, and (second) that there was no reasonable prospect of conviction - represented egregious errors which went beyond an ordinary mistake".
During the hearing, Mr Ross said he believed there was a reasonable prospect of conviction.
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He said evidence from a neighbour which was heard during the civil case had been "confused".
In response, Mr Cameron told the court that the prospect of conviction would have been considered by the Crown in 2011.
Written submissions from Mr Cameron also said that the decision not to prosecute "did not involve an egregious error on the Lord Advocate's part".
Juliette Casey, also acting for Ms Clair, said: "I urge the court, almost 16 years after the allegation of rape and almost 10 years after the civil case, to grant this Bill of Criminal letters."
Goodwillie was represented by Lord Stewart KC, who argued the bill should be refused.
He said there was a potential for prejudicial publicity from the civil case, noting there had not been a warning against self-incrimination at this stage.
Lord Stewart told the court: "The situation at proof was that no criminal proceedings would be taken."
Goodwillie is a former Dundee United, Blackburn, Aberdeen and Plymouth player.
The hearing, before Lord Pentland, Lord Matthews and Lady Carmichael, continues.